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The second law of thermodynamics states that natural processes go in a direction that maintains or increases the total entropy of the universe That is, all things will become more and more disordered unless some action is taken to keep them ordered The increase in entropy and the second law of thermodynamics can be thought of as statements of the probability of events happening Figure 12-15 illustrates an increase in entropy as food-coloring molecules, originally separate from the clear water, are thoroughly mixed with the water molecules over time Figure 12-16 shows an example of the second law of thermodynamics that might be familiar to many teenagers The second law of thermodynamics predicts that heat flows spontaneously only from a hot object to a cold object Consider a hot iron bar and a cold cup of water On the average, the particles in the iron will be moving very fast, whereas the particles in the water will be moving slowly When the bar is plunged into the water and thermal equilibrium is eventually reached, the average kinetic energy of the particles in the iron and the water will be the same More particles now have an increased random motion than was true for the initial state This final state is less ordered than the initial state The fast particles are no longer confined solely to the iron, and the slower particles are no longer confined only to the water; all speeds are evenly distributed The entropy of the final state is greater than that of the initial state Violations of the second law We take for granted many daily events that occur spontaneously, or naturally, in one direction We would be shocked, however, if the reverse of the same events occurred spontaneously You are not surprised when a metal spoon, heated at one end, soon becomes uniformly hot Consider your reaction, however, if a spoon lying on a table suddenly, on its own, became red hot at one end and icy cold at the other If you dive into a swimming pool, you take for granted that you push the water molecules away as you enter the water However, you would be amazed if you were swimming in the pool and all the water molecules spontaneously threw you up onto the diving board Neither of these imagined reverse processes would violate the first law of thermodynamics They are simply examples of the countless events that do not occur because their processes would violate the second law of thermodynamics.
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The second law of thermodynamics and the increase in entropy also give new meaning to what has been commonly called the energy crisis The energy crisis refers to the continued use of limited resources of fossil fuels, such as natural gas and petroleum When you use a resource, such as natural gas to heat your home, you do not use up the energy in the gas As the gas ignites, the internal chemical energy contained in the molecules of the gas is converted into thermal energy of the flame The thermal energy of the flame is then transferred to thermal energy in the air of your home Even if this warm air leaks to the outside, the energy is not lost Energy has not been used up The entropy, however, has increased The chemical structure of natural gas is very ordered As you have learned, when a substance becomes warmer, the average kinetic energy of the particles in the substance increases In contrast, the random motion of warmed air is very disordered While it is mathematically possible for the original chemical order to be reestablished, the probability of this occurring is essentially zero For this reason, entropy often is used as a measure of the unavailability of useful energy The energy in the warmed air in a home is not as available to do mechanical work or to transfer heat to other objects as the original gas molecules were The lack of usable energy is actually a surplus of entropy
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