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A system using a variation of a Foster prism as the polarizer and means for eliminating the contaminating signal from the sky background has been described by Metz (1984) In a later development, Metz (1986) discussed the remedy for the problem of instrumental polarization introduced by the xed superachromatic wave plate which is incorporated after the rotatable one to counter spectral dispersion of the instruments reference axis Compensation for sky contamination was effected in an instrument used by Jain & Srinivasulu (1989) by rotating an eccentrically placed aluminium plate with two semi-circular slots in it, prior to the focal plane of the telescope The principle of the rotating half-wave plate polarimeter has been described earlier in this chapter An instrument using a rotatable achromatic wave plate prior to a Wollaston prism, followed by further geometric separation of the beams, with the signals recorded by photomultipliers and photon counting techniques, has been described by Appenzeller (1967) The design for this is based on that of Hiltner (1959), and is shown in Figure 81, which is in the form of an original sketch by him A dual-beam polarimeter, as sketched out in Figure 84, incorporating a rotatable achromatic wave plate, and capable of spectral studies within stellar line pro les, has been described by Clarke & McLean (1975) For multi-band work, the problem of dispersion of the phase delay of the rotating element was vercome by using a superachromatic design As described in Frecker & Serkowski (1976) such an instrument can be operated over the wavelegth range of 300 nm to 11 m Their system known as MINIPOL , and mentioned earlier, formed the basis of an instrument described by Benedetti (1982) and Magalh es, Benedetti & Roland (1984) which also incorporated a facility for tilt-scanning narrow-band interference lters, following the principles used by Clarke, McLean & Wyllie (1975).

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The two radical concentrations are related by. Make barcode with .net . to generate, create pdf417 2d barcode image in . Much of this is due to experimental dif culties with the rotating sector method s well as the fact that different workers studied polymerizations under widely different reaction conditions. There has been a concerted effort in recent years to bring some order to the situation. A group of polymer scientists organized under the auspices of the IUPAC Working Party on Modeling of Kinetics and Processes of Polymerization has made good progress in this direction by standardization of the reaction conditions for measuring rate constants and the use of the PLPSEC method. Unlike the rotating sector method, the PLP-SEC method allows the measurement of kp directly without the need to couple it to the termination rate constant. The PLP-SEC method, like the rotating sector method, involves a non-steady-state photopolymerization [Beuermann, 2002; Beuermann and Buback, 2002; Kornherr et al., 2003; Nikitin et al., 2002]. Under pulsed laser irradiation, primary radicals are formed in very short times ($10 ns pulse width) compared to the cycle time ($1 s). The laser pulse width is also very short compared to both the lifetimes of propagating radicals and the times for conversion of primary radicals to propagating radicals. The PLP-SEC method for measuring kp requires that reaction conditions be chosen so that no signi cant chain transfer is present. The rst laser pulse generates an almost instantaneous burst of primary radicals at high.Related: 

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