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When radiation passes through a transparent medium, a fraction of the beam scatters in all directions. A small fraction of the scattered radiation differs from the incident beam, showing shifts in wavelength determined by the chemical structure of the molecules in the medium. The same types of quantized vibrational changes associated with IR absorption occur, and the difference in wavelengths between incident and scattered radiations corresponds to wavelengths in the MIR. The Raman scattering spectrum and IR absorption spectrum for a given species are very similar. Figure 11 illustrates a typical Raman spectrum. IR is generally the method of choice, but in some cases Raman spectroscopy offers more information about certain types of organic compounds. For example, it is sensitive to conformational

The Hamiltonian approach focuses from the outset on motion in the 2n-dimensional phase space of the dynamical variables p and q. At the f beginning o our discussion, the variables will indeed resemble the momenta and coordinates of elementary mechanics. But that resemblance will fade as

Like any image editor, Photoshop enables you to alter photographs and other scanned artwork. You can retouch an image, apply special effects, swap details between photos, introduce text and logos, adjust color balance, and even add color to a grayscale scan. Photoshop also provides the tools you need to create images from scratch. These tools are fully compatible with pressure-sensitive tablets, so you can create naturalistic images that look for all the world like watercolors and oils.

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RELATIONSHIP TO PERTURBATION THEORY It should be apparent that the expressions for the wave functions after interaction [equations (3.38) and (3.39)] are equivalent to the Rayleigh Schrodinger perturbation theory (RSPT) result for the perturbed wave function correct to rst order [equation (A.109)]. Similarly, the parallel between the MO energies [equations (3.33) and (3.34)] and the RSPT energy correct to second order [equation (A.110)] is obvious. The ``missing'' rst-order correction emphasizes the correspondence of the rst-order corrected wave function and the second-order corrected energy. Note that equations (3.33), (3.34), (3.38), and (3.39) are valid under the same conditions required for the application of perturbation theory, namely that the perturbation be weak compared to energy di erences.

4. Type in a new path, or use the Ellipsis button to browse to the location. Click OK. 5. From the Reference Manager s toolbar, choose Apply Changes. A summary message appears to confirm that the drawing has been updated. To create a list of references, choose Export Report. In the Export Report dialog box, choose the file type that you want to create from the Files of Type drop-down list. You can create the following file types:

Locating, listing, and activating PCI devices . . . . . . . . . . . . . . . . . . . 273 Locating, listing, and activating USB devices . . . . . . . . . . . . . . . . . . 277 Getting hardware information from the /proc and /sys file systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 278

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Addresses 1 1 AddressId Street City State Zip Persons PersonId FirstName LastName Email 1 AddressId

ften, the first step after you start a new drawing is to set its size and unit type. These and other setup options are discussed in this chapter. The entire process of setting up a drawing is essential for ensuring accurate results. You can save most of these settings in a template to avoid having to recreate them each time you start a new drawing.

This script file starts the CIRCLE command, specifies a center point, and specifies a radius, four times. The results are shown in Figure 30-1.

D.2.4

The statement if expression: begins a control block that executes only if expression is true. You can enclose the expression in parentheses. As far as Python is concerned, the number 0 is false, and any other number is true. Note that in a condition, we use the == operator to test for equality. The = operator is used only for assignments, and assignments are forbidden within a condition. (Here Python differs from C/C++, which allows assignments inside an if-condition, even though they are usually a horrible mistake.) In an if statement, an else-clause executes when the condition is not true. For example:

On the CD-ROM The drawing used in the following exercise drawing circles, ab07-a.dwg, is in the Drawings folder on the CD-ROM.

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